Femtosecond Laser-Induced Underwater Superoleophobic Surfaces with Reversible pH-Responsive Wettability
Wettability-switchable surfaces have become a research hotspot because they can exhibit different superwetting states. In this paper, the copper surfaces with pH-responsive underwater-oil wettability were prepared by femtosecond laser treatment and subsequent chemical modification. The resultant sur...
Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 35(2019), 9 vom: 05. März, Seite 3295-3301 |
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Weitere Verfasser: | , , , |
Format: | Online-Aufsatz |
Sprache: | English |
Veröffentlicht: |
2019
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Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
Schlagworte: | Journal Article |
Zusammenfassung: | Wettability-switchable surfaces have become a research hotspot because they can exhibit different superwetting states. In this paper, the copper surfaces with pH-responsive underwater-oil wettability were prepared by femtosecond laser treatment and subsequent chemical modification. The resultant surfaces showed underwater superoleophobicity in alkaline solutions but quasi-superoleophilicity in acidic solutions. The contact angles of an underwater-oil droplet on the resultant surfaces could be reversibly tuned between 157° and 12° by changing the pH of aqueous solutions. Such switchable wettability is ascribed to the modification of the alkyl and carboxylic acids groups on the laser-structured surfaces. The as-prepared surfaces have both oil-resistance and oil-collection abilities by selectively showing underwater superoleophobicity and superoleophilicity. The smart surfaces with pH-responsive oil wettability will have important applications in controlling the oil behavior in water |
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Beschreibung: | Date Revised 20.11.2019 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
ISSN: | 1520-5827 |
DOI: | 10.1021/acs.langmuir.8b04069 |