|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM292890842 |
| 003 |
DE-627 |
| 005 |
20231225074122.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2019 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/acs.langmuir.8b03838
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n0976.xml
|
| 035 |
|
|
|a (DE-627)NLM292890842
|
| 035 |
|
|
|a (NLM)30661354
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Willott, Joshua D
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Combined Experimental and Theoretical Study of Weak Polyelectrolyte Brushes in Salt Mixtures
|
| 264 |
|
1 |
|c 2019
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 25.02.2020
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a The swelling behavior of a hydrophobic poly(2diisopropylamino)ethyl methacrylate (PDPA) brush immersed in aqueous solutions of single and mixed salts has been investigated using ellipsometry and numerical self-consistent field (nSCF) theory. As a function of solution ionic strength, the osmotic and salted brush regimes of weak polyelectrolyte brushes as well as substantial specific anion effects in the presence of K+ salts of Cl-, NO3-, and SCN- are found. For solutions containing mixtures of NO3- and Cl-, the brush swelling is the same as one would expect on the basis of the concentration-weighted average of the brush behavior in the single salt solutions. However, in mixtures of SCN- and Cl-, the swelling response is more complicated and substantial divergence from ideal behavior is observed. Mean-field theory shows excellent qualitative agreement with the ellipsometry findings. nSCF reveals that for the SCN-/Cl- cases the swelling behavior of the PDPA brush most likely arises from the predominant localization of the weakly hydrated SCN- within the brush compared to the more strongly hydrated Cl-
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Humphreys, Ben A
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Webber, Grant B
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wanless, Erica J
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a de Vos, Wiebe M
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 35(2019), 7 vom: 19. Feb., Seite 2709-2718
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:35
|g year:2019
|g number:7
|g day:19
|g month:02
|g pages:2709-2718
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/acs.langmuir.8b03838
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 35
|j 2019
|e 7
|b 19
|c 02
|h 2709-2718
|