Double-Layer Polymer Electrolyte for High-Voltage All-Solid-State Rechargeable Batteries

© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 31(2019), 4 vom: 30. Jan., Seite e1805574
1. Verfasser: Zhou, Weidong (VerfasserIn)
Weitere Verfasser: Wang, Zhaoxu, Pu, Yuan, Li, Yutao, Xin, Sen, Li, Xiaofang, Chen, Jianfeng, Goodenough, John B
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2019
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article interfaces lithium batteries polymer Li+ conductivity rechargeable batteries
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520 |a No single polymer or liquid electrolyte has a large enough energy gap between the empty and occupied electronic states for both dendrite-free plating of a lithium-metal anode and a Li+ extraction from an oxide host cathode without electrolyte oxidation in a high-voltage cell during the charge process. Therefore, a double-layer polymer electrolyte is investigated, in which one polymer provides dendrite-free plating of a Li-metal anode and the other allows a Li+ extraction from an oxide host cathode without oxidation of the electrolyte in a 4 V cell over a stable charge/discharge cycling at 65 °C; a poly(ethylene oxide) polymer contacts the lithium-metal anode and a poly(N-methyl-malonic amide) contacts the cathode. All interfaces of the flexible, plastic electrolyte remain stable with no visible reduction of the Li+ conductivity on crossing the polymer/polymer interface 
650 4 |a Journal Article 
650 4 |a interfaces 
650 4 |a lithium batteries 
650 4 |a polymer Li+ conductivity 
650 4 |a rechargeable batteries 
700 1 |a Wang, Zhaoxu  |e verfasserin  |4 aut 
700 1 |a Pu, Yuan  |e verfasserin  |4 aut 
700 1 |a Li, Yutao  |e verfasserin  |4 aut 
700 1 |a Xin, Sen  |e verfasserin  |4 aut 
700 1 |a Li, Xiaofang  |e verfasserin  |4 aut 
700 1 |a Chen, Jianfeng  |e verfasserin  |4 aut 
700 1 |a Goodenough, John B  |e verfasserin  |4 aut 
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