Double-Layer Polymer Electrolyte for High-Voltage All-Solid-State Rechargeable Batteries
© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 31(2019), 4 vom: 30. Jan., Seite e1805574 |
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| Weitere Verfasser: | , , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2019
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article interfaces lithium batteries polymer Li+ conductivity rechargeable batteries |
| Zusammenfassung: | © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. No single polymer or liquid electrolyte has a large enough energy gap between the empty and occupied electronic states for both dendrite-free plating of a lithium-metal anode and a Li+ extraction from an oxide host cathode without electrolyte oxidation in a high-voltage cell during the charge process. Therefore, a double-layer polymer electrolyte is investigated, in which one polymer provides dendrite-free plating of a Li-metal anode and the other allows a Li+ extraction from an oxide host cathode without oxidation of the electrolyte in a 4 V cell over a stable charge/discharge cycling at 65 °C; a poly(ethylene oxide) polymer contacts the lithium-metal anode and a poly(N-methyl-malonic amide) contacts the cathode. All interfaces of the flexible, plastic electrolyte remain stable with no visible reduction of the Li+ conductivity on crossing the polymer/polymer interface |
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| Beschreibung: | Date Completed 30.01.2019 Date Revised 01.10.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.201805574 |