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231225s2018 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201704291
|2 doi
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|a pubmed24n0933.xml
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|e rakwb
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|a eng
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1 |
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|a Rubio-Giménez, Víctor
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Bottom-Up Fabrication of Semiconductive Metal-Organic Framework Ultrathin Films
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|c 2018
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 01.08.2018
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|a Date Revised 30.09.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a Though generally considered insulating, recent progress on the discovery of conductive porous metal-organic frameworks (MOFs) offers new opportunities for their integration as electroactive components in electronic devices. Compared to classical semiconductors, these metal-organic hybrids combine the crystallinity of inorganic materials with easier chemical functionalization and processability. Still, future development depends on the ability to produce high-quality films with fine control over their orientation, crystallinity, homogeneity, and thickness. Here self-assembled monolayer substrate modification and bottom-up techniques are used to produce preferentially oriented, ultrathin, conductive films of Cu-CAT-1. The approach permits to fabricate and study the electrical response of MOF-based devices incorporating the thinnest MOF film reported thus far (10 nm thick)
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|a Journal Article
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|a electrical conductivity
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|a metal-organic frameworks
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|a self-assembled monolayers
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|a ultrathin films
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|a Galbiati, Marta
|e verfasserin
|4 aut
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|a Castells-Gil, Javier
|e verfasserin
|4 aut
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|a Almora-Barrios, Neyvis
|e verfasserin
|4 aut
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|a Navarro-Sánchez, José
|e verfasserin
|4 aut
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|a Escorcia-Ariza, Garin
|e verfasserin
|4 aut
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|a Mattera, Michele
|e verfasserin
|4 aut
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|a Arnold, Thomas
|e verfasserin
|4 aut
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|a Rawle, Jonathan
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Tatay, Sergio
|e verfasserin
|4 aut
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|a Coronado, Eugenio
|e verfasserin
|4 aut
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| 700 |
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|a Martí-Gastaldo, Carlos
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 30(2018), 10 vom: 17. März
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|x 1521-4095
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|g volume:30
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|g number:10
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|u http://dx.doi.org/10.1002/adma.201704291
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