Investigation of the Internal Chemical Composition of Chitosan-Based LbL Films by Depth-Profiling X-ray Photoelectron Spectroscopy (XPS) Analysis

Chitosan-based thin films were assembled using the layer-by-layer technique, and the axial composition was accessed using X-ray photoelectron spectroscopy with depth profiling. Chitosan (CHI) samples possessing different degrees of acetylation ([Formula: see text]) and molecular weight ([Formula: se...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 34(2018), 4 vom: 30. Jan., Seite 1429-1440
1. Verfasser: Taketa, Thiago B (VerfasserIn)
Weitere Verfasser: Dos Santos, Danilo M, Fiamingo, Anderson, Vaz, Juliana M, Beppu, Marisa M, Campana-Filho, Sérgio P, Cohen, Robert E, Rubner, Michael F
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2018
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S.
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520 |a Chitosan-based thin films were assembled using the layer-by-layer technique, and the axial composition was accessed using X-ray photoelectron spectroscopy with depth profiling. Chitosan (CHI) samples possessing different degrees of acetylation ([Formula: see text]) and molecular weight ([Formula: see text]) produced via the ultrasound-assisted deacetylation reaction were used in this study along with two different polyanions, namely, sodium polystyrenesulfonate (PSS) and carboxymethylcellulose (CMC). When chitosan, a positively charged polymer in aqueous acid medium, was combined with a strong polyanion (PSS), the total positive charge of chitosan, directly related to its [Formula: see text], was the key factor affecting the film formation. However, for CMC/CHI films, the pH of the medium and [Formula: see text] of chitosan strongly affected the film structure and composition. Consequently, the structure and the axial composition of chitosan-based films can be finely adjusted by choosing the polyanion and defining the chitosan to be used according to its DA and [Formula: see text] for the desired application, as demonstrated by the antibacterial tests 
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650 4 |a Research Support, U.S. Gov't, Non-P.H.S. 
700 1 |a Dos Santos, Danilo M  |e verfasserin  |4 aut 
700 1 |a Fiamingo, Anderson  |e verfasserin  |4 aut 
700 1 |a Vaz, Juliana M  |e verfasserin  |4 aut 
700 1 |a Beppu, Marisa M  |e verfasserin  |4 aut 
700 1 |a Campana-Filho, Sérgio P  |e verfasserin  |4 aut 
700 1 |a Cohen, Robert E  |e verfasserin  |4 aut 
700 1 |a Rubner, Michael F  |e verfasserin  |4 aut 
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