Wrinkling and Periodic Folding of Graphene Oxide Monolayers by Langmuir-Blodgett Compression
Crumples, wrinkles, and other three-dimensional topographical features in graphene oxide (GO) have been of recent interest as these features have improved material performance for a variety of applications. However, wrinkling of monolayer GO films has yet to be reported. Herein, we demonstrate wrink...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 33(2017), 38 vom: 26. Sept., Seite 9880-9888 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
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2017
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't |
| Zusammenfassung: | Crumples, wrinkles, and other three-dimensional topographical features in graphene oxide (GO) have been of recent interest as these features have improved material performance for a variety of applications. However, wrinkling of monolayer GO films has yet to be reported. Herein, we demonstrate wrinkling and folding of monolayer GO using the Langmuir-Blodgett technique for the first time. First, cetyltrimethylammonium bromide (CTAB) and GO are deposited on the air-water interface and uniaxially compressed to form a monolayer. CTAB enhances in-plane rigidity of the monolayer through hydrophobic tail aggregation, preventing GO-GO in-plane sliding behavior. Overcompression of the GO monolayer results in the out-of-plane periodic nanoscale wrinkling and in turn generates folds that are stable during deposition onto a substrate and GO chemical reduction. Furthermore, we investigate one potential application of this material by constructing a 3D electrode of the stacked nanofolded GO-CTAB layers that exhibits superior volumetric capacitance compared to commercial devices and comparable volumetric capacitance compared to high-performing recently reported devices. The high volumetric capacitance is attributed to the electrolyte-accessible channels generated by the nanofolds which are similar in size to the hydrated ions |
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| Beschreibung: | Date Completed 23.07.2018 Date Revised 23.07.2018 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.7b02289 |