Ultrafast Formation of Amorphous Bimetallic Hydroxide Films on 3D Conductive Sulfide Nanoarrays for Large-Current-Density Oxygen Evolution Electrocatalysis
© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 29(2017), 22 vom: 07. Juni |
|---|---|
| 1. Verfasser: | |
| Weitere Verfasser: | , , , , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2017
|
| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article composite materials large current density oxygen evolution reaction, electrocatalysis |
| Zusammenfassung: | © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Developing nonprecious oxygen evolution electrocatalysts that can work well at large current densities is of primary importance in a viable water-splitting technology. Herein, a facile ultrafast (5 s) synthetic approach is reported that produces a novel, efficient, non-noble metal oxygen-evolution nano-electrocatalyst that is composed of amorphous Ni-Fe bimetallic hydroxide film-coated, nickel foam (NF)-supported, Ni3 S2 nanosheet arrays. The composite nanomaterial (denoted as Ni-Fe-OHNi3 S2 /NF) shows highly efficient electrocatalytic activity toward oxygen evolution reaction (OER) at large current densities, even in the order of 1000 mA cm-2 . Ni-Fe-OH@Ni3 S2 /NF also gives an excellent catalytic stability toward OER both in 1 m KOH solution and in 30 wt% KOH solution. Further experimental results indicate that the effective integration of high catalytic reactivity, high structural stability, and high electronic conductivity into a single material system makes Ni-Fe-OH@Ni3 S2 /NF a remarkable catalytic ability for OER at large current densities |
|---|---|
| Beschreibung: | Date Completed 18.07.2018 Date Revised 30.09.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.201700404 |