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231224s2017 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201606264
|2 doi
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|a eng
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|a Zhu, Hui
|e verfasserin
|4 aut
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|a New Mo6 Te6 Sub-Nanometer-Diameter Nanowire Phase from 2H-MoTe2
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|c 2017
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|a Text
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|a ƒaComputermedien
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|a Date Completed 18.07.2018
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|a Date Revised 30.09.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a A novel phase transition, from multilayered 2H-MoTe2 to a parallel bundle of sub-nanometer-diameter metallic Mo6 Te6 nanowires (NWs) driven by catalyzer-free thermal-activation (400-500 °C) under vacuum, is demonstrated. The NWs form along the 〈11-20〉 2H-MoTe2 crystallographic directions with lengths in the micrometer range. The metallic NWs can act as an efficient hole injection layer on top of 2H-MoTe2 due to favorable band-alignment. In particular, an atomically sharp MoTe2 /Mo6 Te6 interface and van der Waals gap with the 2H layers are preserved. The work highlights an alternative pathway for forming a new transition metal dichalcogenide phase and will enable future exploration of its intrinsic transportation properties
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|a annealing
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|a molybdenum ditelluride
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|a nanowires
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|a phase transitions
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|a Wang, Qingxiao
|e verfasserin
|4 aut
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|a Zhang, Chenxi
|e verfasserin
|4 aut
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|a Addou, Rafik
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|a Cho, Kyeongjae
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|a Wallace, Robert M
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|a Kim, Moon J
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|u http://dx.doi.org/10.1002/adma.201606264
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