New Mo6 Te6 Sub-Nanometer-Diameter Nanowire Phase from 2H-MoTe2
© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 29(2017), 18 vom: 17. Mai |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2017
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article annealing molybdenum ditelluride nanowires phase transitions |
| Zusammenfassung: | © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. A novel phase transition, from multilayered 2H-MoTe2 to a parallel bundle of sub-nanometer-diameter metallic Mo6 Te6 nanowires (NWs) driven by catalyzer-free thermal-activation (400-500 °C) under vacuum, is demonstrated. The NWs form along the 〈11-20〉 2H-MoTe2 crystallographic directions with lengths in the micrometer range. The metallic NWs can act as an efficient hole injection layer on top of 2H-MoTe2 due to favorable band-alignment. In particular, an atomically sharp MoTe2 /Mo6 Te6 interface and van der Waals gap with the 2H layers are preserved. The work highlights an alternative pathway for forming a new transition metal dichalcogenide phase and will enable future exploration of its intrinsic transportation properties |
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| Beschreibung: | Date Completed 18.07.2018 Date Revised 30.09.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.201606264 |