Complete 1 H, 13 C{1 H}, and 31 P NMR spectral parameters of some pyrophosphates
Copyright © 2017 John Wiley & Sons, Ltd.
Veröffentlicht in: | Magnetic resonance in chemistry : MRC. - 1985. - 55(2017), 9 vom: 20. Sept., Seite 804-812 |
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1. Verfasser: | |
Format: | Online-Aufsatz |
Sprache: | English |
Veröffentlicht: |
2017
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Zugriff auf das übergeordnete Werk: | Magnetic resonance in chemistry : MRC |
Schlagworte: | Journal Article 13C{1H} 1H 31P NMR iterative spectral analysis molecular modeling pyrophosphates |
Zusammenfassung: | Copyright © 2017 John Wiley & Sons, Ltd. The 1 H, 13 C{1 H}, and 31 P NMR spectral parameters of some pyrophosphates were determined in CDCl3 . The most complicated 1 H spectrum can be solved fully only as (A3 MN)R6 XX'R6 '(MNA3 )', where R6 (= -N(CH3 )2 ) is coupled only to phosphorus (X). Second-order coupling between phosphorus was found and solved with iterative analysis. A signal shape of one of the carbon resonance cannot be explained only with couplings. Explanation for exceptional shape was searched from molecular modeling results. Copyright © 2017 John Wiley & Sons, Ltd |
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Beschreibung: | Date Completed 05.03.2018 Date Revised 05.03.2018 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
ISSN: | 1097-458X |
DOI: | 10.1002/mrc.4590 |