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|a eng
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|a Noirjean, Cecile
|e verfasserin
|4 aut
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|a Nanostructure Changes upon Polymerization of Aqueous and Organic Phases in Organized Mixtures
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|c 2016
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 06.06.2018
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|a Date Revised 06.06.2018
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a The nanostructure of a microemulsion can be strongly affected by the liquid-to-solid transition during polymerization. Here, we examined the evolution of nanostructures of different ternary mixtures, including two microemulsions and a single lamellar phase that upon polymerization are quantitatively studied by SAXS/WAXS and DSC experiments systematically performed before and after the polymerization of both aqueous and organic phases. Samples are mixtures of the poly(2-acrylamido-2-methylpropanesulfonic acid) network as the aqueous phase and poly(hexyl methacrylate) as the organic phase stabilized by Brij35 surfactant. Upon polymerization, the surfactant is excluded from the water/oil interface and crystallizes, strongly changing the nanostructure of samples where it is the main component. In samples where the aqueous phase is the main component, only a few changes in structure are observed upon polymerization. This study demonstrates quantitatively the possibility to preserve nanostructures during polymerization, thus inducing a templating effect
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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1 |
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|a Vancaeyzeele, Cedric
|e verfasserin
|4 aut
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1 |
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|a Bourcier, Sophie
|e verfasserin
|4 aut
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1 |
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|a Testard, Fabienne
|e verfasserin
|4 aut
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1 |
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|a Vidal, Frederic
|e verfasserin
|4 aut
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1 |
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|a Carriere, David
|e verfasserin
|4 aut
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1 |
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|a Fichet, Odile
|e verfasserin
|4 aut
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773 |
0 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1985
|g 32(2016), 39 vom: 04. Okt., Seite 10104-10112
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnas
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773 |
1 |
8 |
|g volume:32
|g year:2016
|g number:39
|g day:04
|g month:10
|g pages:10104-10112
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|e 39
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