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231224s2016 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.6b01874
|2 doi
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|a pubmed24n0873.xml
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|a DE-627
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|e rakwb
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|a eng
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| 100 |
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|a Lin, Shuwei
|e verfasserin
|4 aut
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|a Control of the Handedness of Self-assemblies of Dipeptides by the Chirality of Phenylalanine and Steric Hindrance of Phenylglycine
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|c 2016
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|a Date Completed 05.06.2018
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|a Date Revised 05.06.2018
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a Eight dipeptides, composed of phenylalanine and phenylglycine, that are able to self-assemble into twisted nanoribbons in deionized water are synthesized. The handedness of the nanoribbons is controlled by the chirality of the phenylalanine and the steric hindrance owing to the phenyl group of the phenylglycine. When the phenylalanine is at the C-terminal, π-π stacking by the phenyl groups, hydrogen bonding by the NH group of the phenylalanine, and hydrophobic associations of the alkyl chains control the stacking of the molecules. When phenylglycine is at the C-terminal, the chiral π-π stacking by the phenyl groups of the phenylalanines is suppressed. The hydrogen bonds formed by the NH groups of the phenylalanines had a greater contribution on forming organic self-assemblies than those formed by the NH groups of the phenylglycines
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Dipeptides
|2 NLM
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|a phenylglycine chloride
|2 NLM
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|a 39478-47-2
|2 NLM
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|a Phenylalanine
|2 NLM
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|a 47E5O17Y3R
|2 NLM
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|a Glycine
|2 NLM
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|a TE7660XO1C
|2 NLM
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1 |
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|a Li, Yi
|e verfasserin
|4 aut
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1 |
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|a Li, Baozong
|e verfasserin
|4 aut
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|a Yang, Yonggang
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 32(2016), 29 vom: 26. Juli, Seite 7420-6
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:32
|g year:2016
|g number:29
|g day:26
|g month:07
|g pages:7420-6
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|u http://dx.doi.org/10.1021/acs.langmuir.6b01874
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