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231224s2016 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.6b00289
|2 doi
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|a eng
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|a Tanaka, Toshihiko
|e verfasserin
|4 aut
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| 245 |
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|a Highly Oriented J-Aggregates of Nitroazo Dye and Its Surface-Induced Chromism
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|c 2016
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 18.05.2018
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|a Date Revised 18.05.2018
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Highly oriented J-aggregates of a nitroazo dye were obtained in solid thin films on aligned poly(tetrafluoroethylene) surfaces. During film deposition on a friction-transferred poly(tetrafluoroethylene) layer, a sharp peak grew in the polarized absorption spectra around 613 nm, which was red-shifted 117 nm from the peak in dilute dichloromethane solution. The peak showed remarkable optical anisotropy: dichroic ratios D of up to 22 were observed, and the intrinsic D value should substantially exceed this value. These results indicate that the peak is attributable to highly oriented J-aggregates. On glass, however, H-like aggregates grew, exhibiting an absorption peak at 410 nm. Hence, the substrate surface induced the remarkable chromism observed as a 203 nm red shift
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|a Journal Article
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|a Ishitobi, Masamitsu
|e verfasserin
|4 aut
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|a Aoyama, Tetsuya
|e verfasserin
|4 aut
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|a Matsumoto, Shinya
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 32(2016), 19 vom: 17. Mai, Seite 4710-8
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:32
|g year:2016
|g number:19
|g day:17
|g month:05
|g pages:4710-8
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|u http://dx.doi.org/10.1021/acs.langmuir.6b00289
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