Degradable Polycaprolactone and Polylactide Homopolymer and Block Copolymer Brushes Prepared by Surface-Initiated Polymerization with Triazabicyclodecene and Zirconium Catalysts

Surface-initiated ring-opening polymerization (SI-ROP) of polycaprolactone (PCL) and polylactide (PLA) polymer brushes with controlled degradation rates were prepared on oxide substrates. PCL brushes were polymerized from hydroxyl-terminated monolayers utilizing triazabicyclodecene (TBD) as the poly...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 31(2015), 37 vom: 22. Sept., Seite 10183-9
1. Verfasser: Grubbs, Joe B 3rd (VerfasserIn)
Weitere Verfasser: Arnold, Rachelle M, Roy, Anandi, Durie, Karson, Bilbrey, Jenna A, Gao, Jing, Locklin, Jason
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2015
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Azabicyclo Compounds Polyesters Polymers triazabicyclodecene polycaprolactone 24980-41-4 poly(lactide) 459TN2L5F5 mehr... Zirconium C6V6S92N3C