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231224s2015 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.5b02062
|2 doi
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|a pubmed24n0836.xml
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|a eng
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| 100 |
1 |
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|a Wang, Guoyong
|e verfasserin
|4 aut
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| 245 |
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|a Surface Activity and Aggregation Behavior of Siloxane-Based Ionic Liquids in Aqueous Solution
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|c 2015
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 09.10.2015
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|a Date Revised 04.08.2015
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Six novel siloxane-based surface-active ionic liquids (SAILs)--siloxane ammonium carboxylate [Si(n)N(2)-CA(1), (n = 3, 4)]--were designed and synthesized. Their melting points, surface activities, and self-aggregation behavior in aqueous solution were studied. The results showed that because of the bulky hydrophobic siloxane chains at the end of the tail, all six siloxane-based SAILs are room-temperature ionic liquids (RT-SAILs). The introduction of the siloxane group can reduce the melting point of ionic liquids to below room temperature and can promote the micellization and aggregation behavior more efficiently. These siloxane-based SAILs can greatly reduce the surface tension of water, as shown by the critical aggregation concentration (γCAC) values of 20 mN·m(-1); all six siloxane RT-SAILs can form a vesicle spontaneously in aqueous solution, indicating potential uses as model systems for biomembranes and vehicles for drug delivery
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|a Journal Article
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1 |
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|a Li, Ping
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Du, Zhiping
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Wang, Wanxu
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Li, Guojin
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 31(2015), 30 vom: 04. Aug., Seite 8235-42
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:31
|g year:2015
|g number:30
|g day:04
|g month:08
|g pages:8235-42
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|u http://dx.doi.org/10.1021/acs.langmuir.5b02062
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