Thermal pretreatment of olive mill wastewater for efficient methane production : control of aromatic substances degradation by monitoring cyclohexane carboxylic acid

Anaerobic digestion is investigated as a sustainable depurative strategy of olive oil mill wastewater (OOMW). The effect of thermal pretreatment on the anaerobic biodegradation of aromatic compounds present in (OMWW) was investigated. The anaerobic degradation of phenolic compounds, well known to be...

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Veröffentlicht in:Environmental technology. - 1993. - 36(2015), 13-16 vom: 14. Juli, Seite 1785-94
1. Verfasser: Pontoni, Ludovico (VerfasserIn)
Weitere Verfasser: d'Antonio, Giuseppe, Esposito, Giovanni, Fabbricino, Massimiliano, Frunzo, Luigi, Pirozzi, Francesco
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2015
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article Research Support, Non-U.S. Gov't HS-SPME-GC-MS OOMW management anaerobic digestion benzoyl-CoA pathway thermal treatment Cyclohexanecarboxylic Acids Hydrocarbons, Aromatic Industrial Waste mehr... Olive Oil Plant Oils Waste Water Water Pollutants, Chemical cyclohexanecarboxylic acid H9VKD9VL18 Methane OP0UW79H66
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520 |a Anaerobic digestion is investigated as a sustainable depurative strategy of olive oil mill wastewater (OOMW). The effect of thermal pretreatment on the anaerobic biodegradation of aromatic compounds present in (OMWW) was investigated. The anaerobic degradation of phenolic compounds, well known to be the main concern related to this kind of effluents, was monitored in batch anaerobic tests at a laboratory scale on samples pretreated at mild (80±1 °C), intermediate (90±1 °C) and high temperature (120±1 °C). The obtained results showed an increase of 34% in specific methane production (SMP) for OMWW treated at the lowest temperature and a decrease of 18% for treatment at the highest temperature. These results were related to the different decomposition pathways of the lignocellulosic compounds obtained in the tested conditions. The decomposition pathway was determined by measuring the concentrations of volatile organic acids, phenols, and chemical oxygen demand (COD) versus time. Cyclohexane carboxylic acid (CHCA) production was identified in all the tests with a maximum concentration of around 200 µmol L(-1) in accordance with the phenols degradation, suggesting that anaerobic digestion of aromatic compounds follows the benzoyl-CoA pathway. Accurate monitoring of this compound was proposed as the key element to control the process evolution. The total phenols (TP) and total COD removals were, with SMP, the highest (TP 62.7%-COD 63.2%) at 80 °C and lowest (TP 44.9%-COD 32.2%) at 120 °C. In all cases, thermal pretreatment was able to enhance the TP removal ability (up to 42% increase) 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
650 4 |a HS-SPME-GC-MS 
650 4 |a OOMW management 
650 4 |a anaerobic digestion 
650 4 |a benzoyl-CoA pathway 
650 4 |a thermal treatment 
650 7 |a Cyclohexanecarboxylic Acids  |2 NLM 
650 7 |a Hydrocarbons, Aromatic  |2 NLM 
650 7 |a Industrial Waste  |2 NLM 
650 7 |a Olive Oil  |2 NLM 
650 7 |a Plant Oils  |2 NLM 
650 7 |a Waste Water  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a cyclohexanecarboxylic acid  |2 NLM 
650 7 |a H9VKD9VL18  |2 NLM 
650 7 |a Methane  |2 NLM 
650 7 |a OP0UW79H66  |2 NLM 
700 1 |a d'Antonio, Giuseppe  |e verfasserin  |4 aut 
700 1 |a Esposito, Giovanni  |e verfasserin  |4 aut 
700 1 |a Fabbricino, Massimiliano  |e verfasserin  |4 aut 
700 1 |a Frunzo, Luigi  |e verfasserin  |4 aut 
700 1 |a Pirozzi, Francesco  |e verfasserin  |4 aut 
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773 1 8 |g volume:36  |g year:2015  |g number:13-16  |g day:14  |g month:07  |g pages:1785-94 
856 4 0 |u http://dx.doi.org/10.1080/09593330.2015.1012179  |3 Volltext 
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