A solid-state effect responsible for an organic quintet state at room temperature and ambient pressure

© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 27(2015), 10 vom: 11. März, Seite 1718-23
1. Verfasser: Zheng, Yonghao (VerfasserIn)
Weitere Verfasser: Miao, Mao-sheng, Dantelle, Géraldine, Eisenmenger, Nancy D, Wu, Guang, Yavuz, Ilhan, Chabinyc, Michael L, Houk, Ken N, Wudl, Fred
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2015
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article diradicaloids electron spin resonance photodetectors quintet states
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520 |a A stable organic diradicaloid with an intermolecular quintet at room temperature as a polycrystalline solid is studied. The conclusion is supported by the observation of the ΔMs = ±2 forbidden transition, electron spin resonance (ESR) simulations, and density functional theory (DFT) calculations. In addition, the molecule, as the active component of a device, is an outstanding near-infrared photodetector with detectivity over 10(11) cm Hz(1/2) W(-1) at 1200 nm 
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650 4 |a diradicaloids 
650 4 |a electron spin resonance 
650 4 |a photodetectors 
650 4 |a quintet states 
700 1 |a Miao, Mao-sheng  |e verfasserin  |4 aut 
700 1 |a Dantelle, Géraldine  |e verfasserin  |4 aut 
700 1 |a Eisenmenger, Nancy D  |e verfasserin  |4 aut 
700 1 |a Wu, Guang  |e verfasserin  |4 aut 
700 1 |a Yavuz, Ilhan  |e verfasserin  |4 aut 
700 1 |a Chabinyc, Michael L  |e verfasserin  |4 aut 
700 1 |a Houk, Ken N  |e verfasserin  |4 aut 
700 1 |a Wudl, Fred  |e verfasserin  |4 aut 
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