A solid-state effect responsible for an organic quintet state at room temperature and ambient pressure

A solid-state effect responsible for an organic quintet state at room temperature and ambient pressure

© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 27(2015), 10 vom: 11. März, Seite 1718-23
1. Verfasser: Zheng, Yonghao (VerfasserIn)
Weitere Verfasser: Miao, Mao-sheng, Dantelle, Géraldine, Eisenmenger, Nancy D, Wu, Guang, Yavuz, Ilhan, Chabinyc, Michael L, Houk, Ken N, Wudl, Fred
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2015
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article diradicaloids electron spin resonance photodetectors quintet states
Beschreibung
Zusammenfassung:© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
A stable organic diradicaloid with an intermolecular quintet at room temperature as a polycrystalline solid is studied. The conclusion is supported by the observation of the ΔMs = ±2 forbidden transition, electron spin resonance (ESR) simulations, and density functional theory (DFT) calculations. In addition, the molecule, as the active component of a device, is an outstanding near-infrared photodetector with detectivity over 10(11) cm Hz(1/2) W(-1) at 1200 nm
Beschreibung:Date Completed 11.05.2015
Date Revised 01.10.2020
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1521-4095
DOI:10.1002/adma.201405093