Interplay of metal node and amine functionality in NH2-MIL-53 : modulating breathing behavior through intra-framework interactions
A series of amino-functionalized MIL-53 with different metals as nodes has been synthesized. By determining adsorption properties and spectroscopic characterization, we unequivocally show that the interaction between the amines of the organic linker and bridging μ(2)-OH of the inorganic scaffold mod...
Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 28(2012), 35 vom: 04. Sept., Seite 12916-22 |
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1. Verfasser: | |
Weitere Verfasser: | , , , , , , , , |
Format: | Online-Aufsatz |
Sprache: | English |
Veröffentlicht: |
2012
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Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
Schlagworte: | Journal Article Research Support, Non-U.S. Gov't Amines Organometallic Compounds Carbon Dioxide 142M471B3J |
Zusammenfassung: | A series of amino-functionalized MIL-53 with different metals as nodes has been synthesized. By determining adsorption properties and spectroscopic characterization, we unequivocally show that the interaction between the amines of the organic linker and bridging μ(2)-OH of the inorganic scaffold modulates metal organic framework (MOF) flexibility. The strength of the interaction has been found to correlate with the electropositivity of the metal |
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Beschreibung: | Date Completed 10.01.2013 Date Revised 21.11.2013 published: Print-Electronic Citation Status MEDLINE |
ISSN: | 1520-5827 |
DOI: | 10.1021/la302824j |