Interplay of metal node and amine functionality in NH2-MIL-53 : modulating breathing behavior through intra-framework interactions

A series of amino-functionalized MIL-53 with different metals as nodes has been synthesized. By determining adsorption properties and spectroscopic characterization, we unequivocally show that the interaction between the amines of the organic linker and bridging μ(2)-OH of the inorganic scaffold mod...

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Publié dans:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 28(2012), 35 vom: 04. Sept., Seite 12916-22
Auteur principal: Serra-Crespo, Pablo (Auteur)
Autres auteurs: Gobechiya, Elena, Ramos-Fernandez, Enrique V, Juan-Alcañiz, Jana, Martinez-Joaristi, Alberto, Stavitski, Eli, Kirschhock, Christine E A, Martens, Johan A, Kapteijn, Freek, Gascon, Jorge
Format: Article en ligne
Langue:English
Publié: 2012
Accès à la collection:Langmuir : the ACS journal of surfaces and colloids
Sujets:Journal Article Research Support, Non-U.S. Gov't Amines Organometallic Compounds Carbon Dioxide 142M471B3J