Facile method for the preparation of water dispersible graphene using sulfonated poly(ether-ether-ketone) and its application as energy storage materials

A simple and effective method for the preparation of water dispersible graphene using sulfonated poly(ether-ether-ketone) (SPEEK) has been described. The SPEEK macromolecules are noncovalently adsorbed on the surface of graphene through π-π interactions. The SPEEK-modified graphene (SPG) forms an aq...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 28(2012), 25 vom: 26. Juni, Seite 9825-33
1. Verfasser: Kuila, Tapas (VerfasserIn)
Weitere Verfasser: Mishra, Ananta Kumar, Khanra, Partha, Kim, Nam Hoon, Uddin, Md Elias, Lee, Joong Hee
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a Facile method for the preparation of water dispersible graphene using sulfonated poly(ether-ether-ketone) and its application as energy storage materials 
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520 |a A simple and effective method for the preparation of water dispersible graphene using sulfonated poly(ether-ether-ketone) (SPEEK) has been described. The SPEEK macromolecules are noncovalently adsorbed on the surface of graphene through π-π interactions. The SPEEK-modified graphene (SPG) forms an aqueous dispersion that is stable for more than six months. An analysis of the ultraviolet-visible spectra shows that the aqueous dispersion of SPG obeys Beer's law and the molar extinction coefficient has been found to be 149.03 mL mg(-1) cm(-1). Fourier transform infrared, Raman, and X-ray photoelectron spectroscopy analyses confirm successful reduction and surface modification of graphene. An atomic force microscopy (AFM) analysis reveals the formation of a single layer of functionalized graphene. Transmission electron microscopy results are also in good agreement with the AFM analysis and support the formation of single-layer graphene. SPG shows good electrochemical cyclic stability during cyclic voltammetry and charge/discharge process when used as a supercapacitor electrode. A specific capacitance of 476 F g(-1) at a current density of 6.6 A g(-1) is observed for SPG materials 
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700 1 |a Mishra, Ananta Kumar  |e verfasserin  |4 aut 
700 1 |a Khanra, Partha  |e verfasserin  |4 aut 
700 1 |a Kim, Nam Hoon  |e verfasserin  |4 aut 
700 1 |a Uddin, Md Elias  |e verfasserin  |4 aut 
700 1 |a Lee, Joong Hee  |e verfasserin  |4 aut 
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