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231224s2012 xx |||||o 00| ||eng c |
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|a 10.1021/la300742p
|2 doi
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|a pubmed24n0726.xml
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|a DE-627
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|e rakwb
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|a eng
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|a Huang, Wan-Chen
|e verfasserin
|4 aut
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|a Solvothermal synthesis of zincblende and wurtzite CuInS2 nanocrystals and their photovoltaic application
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|c 2012
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 06.09.2012
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|a Date Revised 05.06.2012
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a We report a simple solvothermal synthesis approach to the growth of CuInS(2) nanocrystals with zincblende- and wurtzite-phase structures. Zincblende nanocrystals with particle sizes of 10-20 nm were produced using oleylamine as the solvent. When ethylenediamine was used as the solvent, similarly sized wurtzite nanocrystals with some degree of particle aggregation were formed. Use of a mixture of these solvents gave products with mixed phases including some polyhedral nanostructures. The crystal phases of these nanocrystals were carefully determined by X-ray diffraction and transmission electron microscopy analysis. All the samples exhibit strong absorption from the entire visible light region to the near-infrared region beyond 1300 nm. Pure-phase zincblende and wurtzite CuInS(2) nanocrystals were employed as ink in the fabrication of solar cells. The spray-coated nanocrystal layer was subjected to a selenization process. A power conversion efficiency of ~0.74% and a good external quantum efficiency profile over broad wavelengths have been measured. The results demonstrate that wurtzite and zincblende CuInS(2) nanocrystals may be attractive precursors to light-absorbing materials for making efficient photovoltaic devices
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|a Journal Article
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|a Tseng, Chih-Hsiao
|e verfasserin
|4 aut
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|a Chang, Shu-Hao
|e verfasserin
|4 aut
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|a Tuan, Hsing-Yu
|e verfasserin
|4 aut
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|a Chiang, Chien-Chih
|e verfasserin
|4 aut
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|a Lyu, Lian-Ming
|e verfasserin
|4 aut
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|a Huang, Michael H
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 28(2012), 22 vom: 05. Juni, Seite 8496-501
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:28
|g year:2012
|g number:22
|g day:05
|g month:06
|g pages:8496-501
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|u http://dx.doi.org/10.1021/la300742p
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