|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM217766331 |
| 003 |
DE-627 |
| 005 |
20231224034832.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231224s2012 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/la300607k
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n0726.xml
|
| 035 |
|
|
|a (DE-627)NLM217766331
|
| 035 |
|
|
|a (NLM)22583353
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Zhu, Yuan
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Synthesis and catalysis of location-specific cobalt nanoparticles supported by multiwall carbon nanotubes for Fischer-Tropsch synthesis
|
| 264 |
|
1 |
|c 2012
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 21.09.2012
|
| 500 |
|
|
|a Date Revised 29.05.2012
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a Cobalt nanoparticles located on the concave internal surface of multiwalled carbon nanotubes (Co-in-MW-CNTs) and the convex external surface of MW-CNTs (Co-on-MW-CNTs) were synthesized. Their catalytic performances in Fischer-Tropsch synthesis (FTS) were investigated. A correlation between the location, pretreatment, and surface chemistry of the cobalt nanoparticles and the catalytic selectivity in FTS was built. It is found that the selectivity in production of C(5+) molecules through FTS on cobalt catalysts supported by MW-CNTs depends on activation temperatures and surface chemistry of the cobalt nanoparticles. A pretreatment at 300 °C in H(2) flow results in a different surface chemistry for Co-in-MW-CNTs than for Co-on-MW-CNTs, which leads to a difference in selectvity to the production of C(5+) molecules. Pretreatment at a relatively high temperature, 400 °C, in H(2) flow produces completely reduced Co nanoparticles in Co-in-MW-CNTs and Co-on-MW-CNTs. There is no signifcant difference in catalytic selectivity between the two catalysts upon pretreatment at 400 °C. The absence of a significant difference in catalytic selectivity of metallic Co-on-MW-CNTs and metallic Co-in-MW-CNTs suggests that the electronic effect of the MW-CNT support does not significantly affect the C(5+) selectivity of cobalt catalysts in FTS
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Ye, Yingchun
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Shiran
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Leong, Mark E
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Tao, Franklin Feng
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 28(2012), 21 vom: 29. Mai, Seite 8275-80
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:28
|g year:2012
|g number:21
|g day:29
|g month:05
|g pages:8275-80
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/la300607k
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 28
|j 2012
|e 21
|b 29
|c 05
|h 8275-80
|