A comparative study of Ag(I) adsorption on raw and modified spent grain : kinetic and thermodynamic aspects

The capability of modified spent grain (MSG) to adsorb silver (I) [Ag(I)] from aqueous solution was investigated and compared with raw spent grain (RSG) regarding their adsorption isotherms, kinetics, and thermodynamics. The monolayer adsorption capacity was 30.28 mg/g for RSG and 158.23 mg/g for MS...

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Veröffentlicht in:Water environment research : a research publication of the Water Environment Federation. - 1998. - 82(2010), 11 vom: 15. Nov., Seite 2290-6
1. Verfasser: Li, Qingzhu (VerfasserIn)
Weitere Verfasser: Chai, Liyuan, Yang, Zhihui, Wang, Qingwei, Wang, Yunyan
Format: Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Water environment research : a research publication of the Water Environment Federation
Schlagworte:Comparative Study Journal Article Research Support, Non-U.S. Gov't Silver 3M4G523W1G
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520 |a The capability of modified spent grain (MSG) to adsorb silver (I) [Ag(I)] from aqueous solution was investigated and compared with raw spent grain (RSG) regarding their adsorption isotherms, kinetics, and thermodynamics. The monolayer adsorption capacity was 30.28 mg/g for RSG and 158.23 mg/g for MSG according to the Langmuir isotherm. The Ag(I) adsorption on MSG was approximately 4 times higher than that on RSG. The pseudo-second-order kinetic model provided the best description of Ag(I) adsorption on the two adsorbents. The calculated activation energy (Ea) implies that the adsorption of Ag(I) on RSG is a physical adsorption and on MSG is of a chemical nature. Thermodynamic results suggest that the adsorption of Ag(I) is an exothermic process for RSG and an endothermic process for MSG, whereas both adsorption processes are spontaneous in nature 
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650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
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700 1 |a Chai, Liyuan  |e verfasserin  |4 aut 
700 1 |a Yang, Zhihui  |e verfasserin  |4 aut 
700 1 |a Wang, Qingwei  |e verfasserin  |4 aut 
700 1 |a Wang, Yunyan  |e verfasserin  |4 aut 
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