A comparative study of Ag(I) adsorption on raw and modified spent grain : kinetic and thermodynamic aspects

The capability of modified spent grain (MSG) to adsorb silver (I) [Ag(I)] from aqueous solution was investigated and compared with raw spent grain (RSG) regarding their adsorption isotherms, kinetics, and thermodynamics. The monolayer adsorption capacity was 30.28 mg/g for RSG and 158.23 mg/g for MS...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Water environment research : a research publication of the Water Environment Federation. - 1998. - 82(2010), 11 vom: 15. Nov., Seite 2290-6
1. Verfasser: Li, Qingzhu (VerfasserIn)
Weitere Verfasser: Chai, Liyuan, Yang, Zhihui, Wang, Qingwei, Wang, Yunyan
Format: Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Water environment research : a research publication of the Water Environment Federation
Schlagworte:Comparative Study Journal Article Research Support, Non-U.S. Gov't Silver 3M4G523W1G
Beschreibung
Zusammenfassung:The capability of modified spent grain (MSG) to adsorb silver (I) [Ag(I)] from aqueous solution was investigated and compared with raw spent grain (RSG) regarding their adsorption isotherms, kinetics, and thermodynamics. The monolayer adsorption capacity was 30.28 mg/g for RSG and 158.23 mg/g for MSG according to the Langmuir isotherm. The Ag(I) adsorption on MSG was approximately 4 times higher than that on RSG. The pseudo-second-order kinetic model provided the best description of Ag(I) adsorption on the two adsorbents. The calculated activation energy (Ea) implies that the adsorption of Ag(I) on RSG is a physical adsorption and on MSG is of a chemical nature. Thermodynamic results suggest that the adsorption of Ag(I) is an exothermic process for RSG and an endothermic process for MSG, whereas both adsorption processes are spontaneous in nature
Beschreibung:Date Completed 04.01.2011
Date Revised 23.09.2019
published: Print
Citation Status MEDLINE
ISSN:1554-7531