A comparative study of Ag(I) adsorption on raw and modified spent grain : kinetic and thermodynamic aspects
The capability of modified spent grain (MSG) to adsorb silver (I) [Ag(I)] from aqueous solution was investigated and compared with raw spent grain (RSG) regarding their adsorption isotherms, kinetics, and thermodynamics. The monolayer adsorption capacity was 30.28 mg/g for RSG and 158.23 mg/g for MS...
Veröffentlicht in: | Water environment research : a research publication of the Water Environment Federation. - 1998. - 82(2010), 11 vom: 15. Nov., Seite 2290-6 |
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Weitere Verfasser: | , , , |
Format: | Aufsatz |
Sprache: | English |
Veröffentlicht: |
2010
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Zugriff auf das übergeordnete Werk: | Water environment research : a research publication of the Water Environment Federation |
Schlagworte: | Comparative Study Journal Article Research Support, Non-U.S. Gov't Silver 3M4G523W1G |
Zusammenfassung: | The capability of modified spent grain (MSG) to adsorb silver (I) [Ag(I)] from aqueous solution was investigated and compared with raw spent grain (RSG) regarding their adsorption isotherms, kinetics, and thermodynamics. The monolayer adsorption capacity was 30.28 mg/g for RSG and 158.23 mg/g for MSG according to the Langmuir isotherm. The Ag(I) adsorption on MSG was approximately 4 times higher than that on RSG. The pseudo-second-order kinetic model provided the best description of Ag(I) adsorption on the two adsorbents. The calculated activation energy (Ea) implies that the adsorption of Ag(I) on RSG is a physical adsorption and on MSG is of a chemical nature. Thermodynamic results suggest that the adsorption of Ag(I) is an exothermic process for RSG and an endothermic process for MSG, whereas both adsorption processes are spontaneous in nature |
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Beschreibung: | Date Completed 04.01.2011 Date Revised 23.09.2019 published: Print Citation Status MEDLINE |
ISSN: | 1554-7531 |