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231223s2010 xx |||||o 00| ||eng c |
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|a 10.1021/la9047819
|2 doi
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|a pubmed24n0652.xml
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|a (NLM)20210337
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|a DE-627
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|a eng
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| 100 |
1 |
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|a Zhao, Yu
|e verfasserin
|4 aut
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|a Effect of inclusion complexation with cyclodextrin on the cloud point of poly(2-(dimethylamino)ethyl methacrylate) solution
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|c 2010
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 08.09.2010
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|a Date Revised 26.05.2010
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a We investigated the influence of addition of cyclodextrin (CD) on the cloud point of poly(2-(dimethylamino)ethyl methacrylate) (PDMAEMA) aqueous solution. Both beta-CD and randomly methylated beta-cyclodextrin (RM-beta-CD) raised the cloud point of PDMAEMA solution; by contrast, the addition of alpha-CD or gamma-CD did not affect the cloud point of PDMAEMA solution. The inclusion complexation between side group of PDMAEMA and RM-beta-CD was confirmed by NMR experiments. The cloud point of PDMAEMA solution was raised gradually with the increase of concentration of RM-beta-CD. On the basis of inclusion complexation equilibrium, we deduced an equation, which clearly described the relationship between cloud point and concentration of RM-beta-CD. This analysis will provide an important theoretic guide for other related research. In comparison with copolymerization with another monomer, such a supramolecular approach avoids a series of synthesis and facilitates fine-tuning of cloud point
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|a Journal Article
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|a Guo, Kai
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Wang, Chunyu
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Wang, Liyan
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 26(2010), 11 vom: 01. Juni, Seite 8966-70
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
1 |
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|g volume:26
|g year:2010
|g number:11
|g day:01
|g month:06
|g pages:8966-70
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|u http://dx.doi.org/10.1021/la9047819
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