Nanometer-scale wetting of the silicon surface by its equilibrium oxide

Despite the extremely broad technical applications of the Si/SiO2 structure, the equilibrium wetting properties of silicon oxide on silicon are poorly understood. Here, we produce new results in which a solid-state buffer method is used to systematically titrate oxygen activity about the Si/SiO2 coe...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 24(2008), 5 vom: 04. März, Seite 1891-6
1. Verfasser: Tang, Ming (VerfasserIn)
Weitere Verfasser: Ramos, Ana V, Jud, Eva, Chung, Sung-Yoon, Gautier-Soyer, Martine, Cannon, Rowland M, Carter, W Craig, Chiang, Yet-Ming
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2008
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Despite the extremely broad technical applications of the Si/SiO2 structure, the equilibrium wetting properties of silicon oxide on silicon are poorly understood. Here, we produce new results in which a solid-state buffer method is used to systematically titrate oxygen activity about the Si/SiO2 coexistence value. The equilibrium morphology at the Si(001) surface over >8 decades of PO2 about coexistence is revealed to be a uniform sub-stoichiometric SiOx film of sub-nanometer thickness, coexisting with secondary island structures which coarsen with annealing time. A new thermodynamic method using chemical potential to stabilize and control surficial oxides in nanoscale devices is suggested 
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700 1 |a Ramos, Ana V  |e verfasserin  |4 aut 
700 1 |a Jud, Eva  |e verfasserin  |4 aut 
700 1 |a Chung, Sung-Yoon  |e verfasserin  |4 aut 
700 1 |a Gautier-Soyer, Martine  |e verfasserin  |4 aut 
700 1 |a Cannon, Rowland M  |e verfasserin  |4 aut 
700 1 |a Carter, W Craig  |e verfasserin  |4 aut 
700 1 |a Chiang, Yet-Ming  |e verfasserin  |4 aut 
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