Coordinated NH3-removal-induced hydrogen adsorption of Cu-complex crystals

We synthesized a discrete type of organic-inorganic hybrid crystal [Cu(ina)2(NH3)2(H2O)2] (ina = isonicotinate). The monomer units connect to each other with hydrogen bonds and pi-pi interactions, forming a three-dimensional network. Removal of ammonia and water molecules by vacuum heating treatment...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 24(2008), 1 vom: 01. Jan., Seite 170-4
1. Verfasser: Kondo, Atsushi (VerfasserIn)
Weitere Verfasser: Noguchi, Hiroshi, Kajiro, Hiroshi, Ohba, Tomonori, Kaneko, Katsumi, Kanoh, Hirofumi
Format: Aufsatz
Sprache:English
Veröffentlicht: 2008
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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100 1 |a Kondo, Atsushi  |e verfasserin  |4 aut 
245 1 0 |a Coordinated NH3-removal-induced hydrogen adsorption of Cu-complex crystals 
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520 |a We synthesized a discrete type of organic-inorganic hybrid crystal [Cu(ina)2(NH3)2(H2O)2] (ina = isonicotinate). The monomer units connect to each other with hydrogen bonds and pi-pi interactions, forming a three-dimensional network. Removal of ammonia and water molecules by vacuum heating treatment induced a substantial change from nonporous to porous crystals. The resultant porous crystals can predominantly adsorb supercritical hydrogen rather than nitrogen vapor at 77 K 
650 4 |a Journal Article 
700 1 |a Noguchi, Hiroshi  |e verfasserin  |4 aut 
700 1 |a Kajiro, Hiroshi  |e verfasserin  |4 aut 
700 1 |a Ohba, Tomonori  |e verfasserin  |4 aut 
700 1 |a Kaneko, Katsumi  |e verfasserin  |4 aut 
700 1 |a Kanoh, Hirofumi  |e verfasserin  |4 aut 
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