Coordinated NH3-removal-induced hydrogen adsorption of Cu-complex crystals
We synthesized a discrete type of organic-inorganic hybrid crystal [Cu(ina)2(NH3)2(H2O)2] (ina = isonicotinate). The monomer units connect to each other with hydrogen bonds and pi-pi interactions, forming a three-dimensional network. Removal of ammonia and water molecules by vacuum heating treatment...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1999. - 24(2008), 1 vom: 01. Jan., Seite 170-4 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , |
| Format: | Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2008
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | We synthesized a discrete type of organic-inorganic hybrid crystal [Cu(ina)2(NH3)2(H2O)2] (ina = isonicotinate). The monomer units connect to each other with hydrogen bonds and pi-pi interactions, forming a three-dimensional network. Removal of ammonia and water molecules by vacuum heating treatment induced a substantial change from nonporous to porous crystals. The resultant porous crystals can predominantly adsorb supercritical hydrogen rather than nitrogen vapor at 77 K |
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| Beschreibung: | Date Completed 03.04.2008 Date Revised 26.12.2007 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |