Fabrication of electrochemical transistor based on pi-conjugate polymer Langmuir-Blodgett film

We fabricated an efficient organic electrochemical transistor (OECT) composed of polymer Langmuir-Blodgett (LB) film. The pi-conjugated polymer LB film, which was constructed from a poly(N-dodecylacrylamide) (pDDA) and poly(3-hexylthiophene) (PHT) mixture, was used as a conduction channel layer to c...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1991. - 23(2007), 16 vom: 31. Juli, Seite 8602-6
1. Verfasser: Matsui, Jun (VerfasserIn)
Weitere Verfasser: Sato, Yoshitaka, Mikayama, Takeshi, Miyashita, Tokuji
Format: Aufsatz
Sprache:English
Veröffentlicht: 2007
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Membranes, Artificial Polyethylenes Quaternary Ammonium Compounds poly-N,N-dimethyl-N,N-diallylammonium chloride 26062-79-3
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245 1 0 |a Fabrication of electrochemical transistor based on pi-conjugate polymer Langmuir-Blodgett film 
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500 |a Date Revised 19.11.2009 
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520 |a We fabricated an efficient organic electrochemical transistor (OECT) composed of polymer Langmuir-Blodgett (LB) film. The pi-conjugated polymer LB film, which was constructed from a poly(N-dodecylacrylamide) (pDDA) and poly(3-hexylthiophene) (PHT) mixture, was used as a conduction channel layer to connect source and drain electrodes. The mixed-polymer LB film was characterized using UV-vis spectroscopy, X-ray diffraction (XRD), atomic force microscopy (AFM), and cyclic voltammetry. Subsequent UV spectra measurements, XRD measurements, and AFM measurements show that PHT forms a crystalline lamellar domain in the layered structure of pDDA. The OECT included 10 layers of the mixed-polymer LB film as the conduction channel layer. The OECT showed an on/off ratio of 1.1x10(4) and mobility of 7.5x10(-2) cm2 V(-1) s(-1) at low gate (VG=-1.2 V) and source-drain voltages (VDS=-0.5 V). Moreover, the necessary charge to operate the OECT was 1.1x10(-9) mol of e(-1) cm(-2), which was 2 orders smaller than the value reported using a similar device structure. The relatively high on/off ratio and low charge consumption suggest that this OECT, which is fabricated from pi-conjugated polymer LB films, is applicable to macroelectronic devices 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
650 7 |a Membranes, Artificial  |2 NLM 
650 7 |a Polyethylenes  |2 NLM 
650 7 |a Quaternary Ammonium Compounds  |2 NLM 
650 7 |a poly-N,N-dimethyl-N,N-diallylammonium chloride  |2 NLM 
650 7 |a 26062-79-3  |2 NLM 
700 1 |a Sato, Yoshitaka  |e verfasserin  |4 aut 
700 1 |a Mikayama, Takeshi  |e verfasserin  |4 aut 
700 1 |a Miyashita, Tokuji  |e verfasserin  |4 aut 
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