Plasma-induced formation of Ag nanodots for ultra-high-enhancement surface-enhanced Raman scattering substrates
We report here plasma-induced formation of Ag nanostructures for surface-enhanced Raman scattering (SERS) applications. An array of uniform Ag patterned structures of 150 nm diameter was first fabricated on a silicon substrate with imprint lithography; then the substrate was further treated with an...
Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1999. - 23(2007), 9 vom: 24. Apr., Seite 5135-8 |
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1. Verfasser: | |
Weitere Verfasser: | , , , , , , , |
Format: | Aufsatz |
Sprache: | English |
Veröffentlicht: |
2007
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Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
Schlagworte: | Journal Article Research Support, U.S. Gov't, Non-P.H.S. 4-mercaptophenol Phenols Sulfhydryl Compounds Silver 3M4G523W1G Oxygen S88TT14065 Silicon |
Zusammenfassung: | We report here plasma-induced formation of Ag nanostructures for surface-enhanced Raman scattering (SERS) applications. An array of uniform Ag patterned structures of 150 nm diameter was first fabricated on a silicon substrate with imprint lithography; then the substrate was further treated with an oxygen plasma to fracture the patterned structures into clusters of smaller, interconnected, closely packed Ag nanoparticles (20-60 nm) and redeposited Ag nanodots ( approximately 10 nm) between the clusters. The substrate thus formed had a uniform ultrahigh SERS enhancement factor (1010) over the entire substrate for 4-mercaptophenol molecules. By comparison, Au patterned structures fabricated with the same method did not undergo such a morphological change after the plasma treatment and showed no enhancement of Raman scattering |
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Beschreibung: | Date Completed 12.06.2007 Date Revised 21.11.2013 published: Print-Electronic Citation Status MEDLINE |
ISSN: | 1520-5827 |