Site specificity of alpha-H abstraction reaction among secondary structure motif--an ab initio study
The initial step of protein oxidation is studied through alpha-H abstraction by an OH radical with various secondary structure motifs of proteins. It is found that there exist preferential alpha-Hs in this kind of abstractions. The typical abstraction mechanism involves three steps: forming a pre-re...
| Publié dans: | Journal of computational chemistry. - 1984. - 28(2007), 4 vom: 01. März, Seite 783-94 |
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| Auteur principal: | |
| Autres auteurs: | , |
| Format: | Article |
| Langue: | English |
| Publié: |
2007
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| Accès à la collection: | Journal of computational chemistry |
| Sujets: | Journal Article Research Support, Non-U.S. Gov't Peptides Proteins Hydrogen 7YNJ3PO35Z |