Thin films of bicontinuous cubic mesostructured silica templated by a nonionic surfactant

Thin films ofbicontinuous cubic mesostructured silica were formed using the nonionic poly(oxyethylene)-alkyl ether surfactant Brij-56 as a structure-directing agent. The synthesis conditions were chosen such that the estimated volume fraction of surfactant in the silica/surfactant films corresponded...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 20(2004), 14 vom: 06. Juli, Seite 5998-6004
1. Verfasser: Hayward, Ryan C (VerfasserIn)
Weitere Verfasser: Alberius, Peter C A, Kramer, Edward J, Chmelka, Bradley F
Format: Aufsatz
Sprache:English
Veröffentlicht: 2004
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a Thin films of bicontinuous cubic mesostructured silica templated by a nonionic surfactant 
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520 |a Thin films ofbicontinuous cubic mesostructured silica were formed using the nonionic poly(oxyethylene)-alkyl ether surfactant Brij-56 as a structure-directing agent. The synthesis conditions were chosen such that the estimated volume fraction of surfactant in the silica/surfactant films corresponded approximately to the composition at which the bicontinuous cubic phase occurs in the water/surfactant phase diagram. Small-angle X-ray scattering and transmission electron microscopy measurements reveal that the cubic phase corresponds to the Ia3(-)d double-gyroid structure, with some distortion due to anisotropic film shrinkage. The cubic structure grows as faceted domains that are well-oriented with respect to the substrate and often occur in coexistence with a lamellar phase. By adjusting the temperature at which the films are aged, it is possible to create films with 2D hexagonal, cubic, or lamellar structures at a single composition 
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700 1 |a Kramer, Edward J  |e verfasserin  |4 aut 
700 1 |a Chmelka, Bradley F  |e verfasserin  |4 aut 
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