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|a DE-627
|b ger
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|e rakwb
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|a eng
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|a Hayward, Ryan C
|e verfasserin
|4 aut
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|a Thin films of bicontinuous cubic mesostructured silica templated by a nonionic surfactant
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|c 2004
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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|a Band
|b nc
|2 rdacarrier
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|a Date Completed 20.03.2007
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|a Date Revised 26.10.2019
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a Thin films ofbicontinuous cubic mesostructured silica were formed using the nonionic poly(oxyethylene)-alkyl ether surfactant Brij-56 as a structure-directing agent. The synthesis conditions were chosen such that the estimated volume fraction of surfactant in the silica/surfactant films corresponded approximately to the composition at which the bicontinuous cubic phase occurs in the water/surfactant phase diagram. Small-angle X-ray scattering and transmission electron microscopy measurements reveal that the cubic phase corresponds to the Ia3(-)d double-gyroid structure, with some distortion due to anisotropic film shrinkage. The cubic structure grows as faceted domains that are well-oriented with respect to the substrate and often occur in coexistence with a lamellar phase. By adjusting the temperature at which the films are aged, it is possible to create films with 2D hexagonal, cubic, or lamellar structures at a single composition
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|a Journal Article
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|a Alberius, Peter C A
|e verfasserin
|4 aut
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|a Kramer, Edward J
|e verfasserin
|4 aut
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|a Chmelka, Bradley F
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 20(2004), 14 vom: 06. Juli, Seite 5998-6004
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:20
|g year:2004
|g number:14
|g day:06
|g month:07
|g pages:5998-6004
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|d 20
|j 2004
|e 14
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|h 5998-6004
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