Shear-induced orientation of a rigid surfactant mesophase
An optically clear, crystalline, gel-like mesophase is formed by the addition of water to a micellar solution consisting of a mixture of 0.85 M anionic surfactant sodium bis(2-ethylhexyl) sulfosuccinate (AOT) and a 0.42 M zwitterionic surfactant phosphatidylcholine (lecithin) in isooctane. At 25 deg...
Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 20(2004), 14 vom: 06. Juli, Seite 5693-702 |
---|---|
1. Verfasser: | |
Weitere Verfasser: | , , , , |
Format: | Aufsatz |
Sprache: | English |
Veröffentlicht: |
2004
|
Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
Schlagworte: | Journal Article |
Zusammenfassung: | An optically clear, crystalline, gel-like mesophase is formed by the addition of water to a micellar solution consisting of a mixture of 0.85 M anionic surfactant sodium bis(2-ethylhexyl) sulfosuccinate (AOT) and a 0.42 M zwitterionic surfactant phosphatidylcholine (lecithin) in isooctane. At 25 degrees C and water to AOT molar ratio of 70, the system has a columnar hexagonal microstructure with randomly oriented domains. The shear-induced orientation and subsequent relaxation of this structure were investigated by rheological characterization and small-angle neutron scattering (SANS). The rheological response implies that the domains align under shear, and remain aligned for several hours after cessation of shear. Shear-SANS confirms this picture. The sheared gel mesophase retains its alignment as the temperature is increased to 57 degrees C, indicating the potential to conduct templated polymer and polymer-ceramic composite materials synthesis in aligned systems |
---|---|
Beschreibung: | Date Completed 20.03.2007 Date Revised 26.10.2019 published: Print Citation Status PubMed-not-MEDLINE |
ISSN: | 1520-5827 |