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231223s2004 xx ||||| 00| ||eng c |
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|a (NLM)15969143
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|a DE-627
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|c DE-627
|e rakwb
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| 041 |
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|a eng
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| 100 |
1 |
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|a Hanrahan, John P
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Water-in-CO2 emulsions
|b reaction vessels for the production of tetra-ethyl pyrone
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| 264 |
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|c 2004
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| 336 |
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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| 338 |
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|b nc
|2 rdacarrier
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|a Date Completed 12.01.2006
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|a Date Revised 26.10.2019
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a Water-in-CO2 (W/C) emulsions formed using a nickel Triton X-100 surfactant complex (Ni-surfactant) were used as microreactors for the carbon-carbon coupling reaction between hex-3-yne and CO2 to produce tetra-ethyl pyrone (TEP). The structure of the product, which was isolated in the CO2 phase, was determined using gas chromatography mass spectrometry (GC-MS) and infrared spectroscopy. The Ni-surfactant acted as both an emulsion forming agent and a water soluble catalyst for this carbon-carbon coupling reaction. The optimum yield of TEP was determined to be 69% after 72 h, at a temperature of 70 degrees C and a pressure of 206 bar. The ease with which the emulsion could be collapsed allowed the facile separation of products from the catalyst and any unreacted starting material. Product selectivity in the W/C emulsions was found to be greater than that obtained using conventional organic methodologies
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|a Journal Article
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|a Ziegler, Kirk J
|e verfasserin
|4 aut
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1 |
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|a Galvin, John P
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Holmes, Justin D
|e verfasserin
|4 aut
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| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 20(2004), 11 vom: 25. Mai, Seite 4386-90
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
1 |
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|g volume:20
|g year:2004
|g number:11
|g day:25
|g month:05
|g pages:4386-90
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| 952 |
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|d 20
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|h 4386-90
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