Water-in-CO2 emulsions : reaction vessels for the production of tetra-ethyl pyrone
Water-in-CO2 (W/C) emulsions formed using a nickel Triton X-100 surfactant complex (Ni-surfactant) were used as microreactors for the carbon-carbon coupling reaction between hex-3-yne and CO2 to produce tetra-ethyl pyrone (TEP). The structure of the product, which was isolated in the CO2 phase, was...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 20(2004), 11 vom: 25. Mai, Seite 4386-90 |
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| Format: | Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2004
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | Water-in-CO2 (W/C) emulsions formed using a nickel Triton X-100 surfactant complex (Ni-surfactant) were used as microreactors for the carbon-carbon coupling reaction between hex-3-yne and CO2 to produce tetra-ethyl pyrone (TEP). The structure of the product, which was isolated in the CO2 phase, was determined using gas chromatography mass spectrometry (GC-MS) and infrared spectroscopy. The Ni-surfactant acted as both an emulsion forming agent and a water soluble catalyst for this carbon-carbon coupling reaction. The optimum yield of TEP was determined to be 69% after 72 h, at a temperature of 70 degrees C and a pressure of 206 bar. The ease with which the emulsion could be collapsed allowed the facile separation of products from the catalyst and any unreacted starting material. Product selectivity in the W/C emulsions was found to be greater than that obtained using conventional organic methodologies |
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| Beschreibung: | Date Completed 12.01.2006 Date Revised 26.10.2019 published: Print Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |