X-ray absorption spectroscopy to probe surface composition and surface deprotection in photoresist films

Near-edge X-ray absorption fine structure spectroscopy (NEXAFS) is utilized to provide insight into surface chemical effects in model photoresist films. First, NEXAFS was used to examine the resist/air interface including surface segregation of a photoacid generator (PAG) and the extent of surface d...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 21(2005), 9 vom: 26. Apr., Seite 4007-15
1. Verfasser: Lenhart, Joseph L (VerfasserIn)
Weitere Verfasser: Fischer, Daniel A, Sambasivan, Sharadha, Lin, Eric K, Jones, Ronald L, Soles, Christopher L, Wu, Wen-Li, Goldfarb, Dario L, Angelopoulos, Marie
Format: Aufsatz
Sprache:English
Veröffentlicht: 2005
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
Beschreibung
Zusammenfassung:Near-edge X-ray absorption fine structure spectroscopy (NEXAFS) is utilized to provide insight into surface chemical effects in model photoresist films. First, NEXAFS was used to examine the resist/air interface including surface segregation of a photoacid generator (PAG) and the extent of surface deprotection in the film. The concentration of PAG at the resist-air interface was higher than the bulk concentration, which led to a faster deprotection rate at that interface. Second, a NEXAFS depth profiling technique was utilized to probe for compositional gradients in model resist line edge regions. In the model line edge region, the surface composition profile for the developed line edge was dependent on the post exposure bake time
Beschreibung:Date Completed 28.07.2006
Date Revised 19.04.2005
published: Print
Citation Status PubMed-not-MEDLINE
ISSN:1520-5827