|
|
|
|
| LEADER |
01000naa a22002652c 4500 |
| 001 |
NLM394200411 |
| 003 |
DE-627 |
| 005 |
20251017233653.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
251017s2025 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202512997
|2 doi
|
| 028 |
5 |
2 |
|a pubmed25n1602.xml
|
| 035 |
|
|
|a (DE-627)NLM394200411
|
| 035 |
|
|
|a (NLM)41104700
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Chen, Yuxuan
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Regulation of Interfacial Ion Transport via Honeycomb-Architected Covalent Organic Frameworks for Lithium Metal Batteries
|
| 264 |
|
1 |
|c 2025
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 17.10.2025
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status Publisher
|
| 520 |
|
|
|a © 2025 Wiley‐VCH GmbH.
|
| 520 |
|
|
|a This study pioneers vertically aligned honeycomb covalent organic framework (HCCOF) on graphene oxide (HCCOF-GO) through one-pot colloidal assembly, establishing a paradigm for interface-engineered 2D heterostructures in lithium metal batteries (LMBs). Mechanistically, the vertical COF alignment via interfacial π-π conjugation preserves intrinsic 1.15 nm hexagonal pores while integrating Go's electron transport capabilities. When deployed as an artificial solid-electrolyte interphase (ASEI), this architecture demonstrates triple functionalities: i) "lithiophilic" nanopores enabling dendrite-free Li+ flux (migration barrier 0.29 eV), ii) polarized interfaces regulating anion-solvent coordination, and iii) gradient organic-inorganic solid electrolyte interphase (SEI) formation. The modified anodes achieve record Li+ transference number (tLi + = 0.96) with ultra-long cyclability (>3000 h at 10 mA cm-2, 10 mAh cm-2) and minimal polarization (ΔV = 13 mV). Competitive electrochemical performance across diverse battery configurations confirms practical viability: the HCCOF-GOLi‖NCM811 full cell retains 81.1% of its initial capacity after 100 cycles at a practical loading of 4.5 mAh cm-2. Corresponding pouch cells (368 Wh kg-1) maintain 82.3% capacity retention after 40 cycles, while HCCOF-GO@Li‖LCO cell demonstrates remarkable cycling stability (500 cycles@80.3%) at a high voltage of 4.7 V
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a anion‐solvent regulation
|
| 650 |
|
4 |
|a artificial solid‐electrolyte interphase
|
| 650 |
|
4 |
|a honeycomb covalent organic framework
|
| 650 |
|
4 |
|a interfacial Ï€‐Ï€ conjugation
|
| 650 |
|
4 |
|a lithium metal batteries
|
| 700 |
1 |
|
|a He, Jie
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Mengjun
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Shen, Huasen
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Han, Chi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Tian, Yunan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wu, Xiaoxin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Yuansheng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Ting
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Xuanxuan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Yuyu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Bu, Fanxing
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Xie, Ming
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Zhaohuai
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g (2025) vom: 17. Okt., Seite e12997
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnas
|
| 773 |
1 |
8 |
|g year:2025
|g day:17
|g month:10
|g pages:e12997
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202512997
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|j 2025
|b 17
|c 10
|h e12997
|