|
|
|
|
| LEADER |
01000naa a22002652c 4500 |
| 001 |
NLM393750701 |
| 003 |
DE-627 |
| 005 |
20251008232412.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
251008s2025 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202513320
|2 doi
|
| 028 |
5 |
2 |
|a pubmed25n1593.xml
|
| 035 |
|
|
|a (DE-627)NLM393750701
|
| 035 |
|
|
|a (NLM)41058543
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Zhang, Ze-Nong
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Low-Voltage Driven Co-Production of Ammonia, Formate, and Hydrogen From Nitrite Reduction Coupled Formaldehyde Oxidation System on Ultra-Stable AuCuRh Nanowires under Illumination
|
| 264 |
|
1 |
|c 2025
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 08.10.2025
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status Publisher
|
| 520 |
|
|
|a © 2025 Wiley‐VCH GmbH.
|
| 520 |
|
|
|a The nitrite electroreduction reaction (NO2RR) offers a green and sustainable pathway for environmental wastewater treatment and ammonia (NH3) generation. Herein, defect-rich trimetallic AuCuRh nanowires (AuCuRh NWs) with a large number of grain boundaries, twin boundaries, and atomic steps are successfully synthesized by galvanic replacement reaction. Due to its self-stability and high activity, AuCuRh NWs can efficiently drive the stable NO2RR at 0 V potential (Faradaic efficiency: 98.32%, NH3 yield rate: 20.49 mg h-1 mgcat -1). Moreover, AuCuRh NWs also reveal excellent electrocatalytic activity for the formaldehyde electrooxidation reaction (FOR), which can reach 10 mA cm-2 at only 0.35 V potential. The NO2RR||FOR electrolysis system assembled with AuCuRh NWs requires only the electrolysis voltage of 0.38 V to achieve the co-production of NH3, formate, and hydrogen and ultra-stable continuous electrolysis for 300 hours. The NO2RR||FOR electrolysis system can be further decreased to only 0.29 V under illumination due to plasmon-enhanced activity. This study provides an energy-efficient coupling strategy for the stable co-production of value-added chemicals
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a coupled system
|
| 650 |
|
4 |
|a electrolysis
|
| 650 |
|
4 |
|a formaldehyde oxidation
|
| 650 |
|
4 |
|a nitrite reduction
|
| 650 |
|
4 |
|a value‐added products
|
| 700 |
1 |
|
|a Wang, Xiao-Hui
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhong, Wei
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ai, Xuan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Xin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Shu-Ni
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Xia, Bao Yu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chen, Yu
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g (2025) vom: 08. Okt., Seite e13320
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnas
|
| 773 |
1 |
8 |
|g year:2025
|g day:08
|g month:10
|g pages:e13320
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202513320
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|j 2025
|b 08
|c 10
|h e13320
|