Advanced Electrolyte Engineering for Low-Temperature Sodium-Ion Batteries

© 2025 Wiley‐VCH GmbH.

Détails bibliographiques
Publié dans:Advanced materials (Deerfield Beach, Fla.). - 1998. - (2025) vom: 15. Sept., Seite e13868
Auteur principal: Yang, Yi (Auteur)
Autres auteurs: Yang, Yongjian, Yang, Yang, Yao, Yu, Yang, Hai, Wu, Zhijun, He, Shengnan, Pan, Hongge, Fang, Shaoming, Rui, Xianhong, Yu, Yan
Format: Article en ligne
Langue:English
Publié: 2025
Accès à la collection:Advanced materials (Deerfield Beach, Fla.)
Sujets:Journal Article Review electrolytes interfacial chemistry low‐temperature performance sodium‐ion batteries solvation structure
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520 |a Given the abundance and low cost of sodium resources, sodium-ion batteries (SIBs) are considered promising alternatives to lithium-ion batteries (LIBs). Moreover, the unique electrochemical and chemical characteristics of SIBs indicate their substantial potential for low-temperature operation. However, low temperatures significantly reduce the intrinsic Na+ transport rate, sharply increase the Na+ de-solvation energy barrier at the battery-electrolyte interface, and lead to dynamic solid electrolyte interphase (SEI) reconstruction, resulting in a substantial increase in interfacial impedance. These issues ultimately lead to severe capacity degradation, diminished power performance, shortened cycle life, and even complete battery failure at low temperatures. To address these challenges, this review thoroughly analyzes the failure mechanisms of electrolytes at low temperatures and comprehensively summarizes current design and optimization strategies for low-temperature SIB electrolytes, including solvent engineering, concentration regulation, novel additives and sodium salts, and emerging electrolyte systems. Furthermore, it prospects the future development trends of organic electrolytes, aiming to provide insights for the advancement of novel low-temperature SIBs 
650 4 |a Journal Article 
650 4 |a Review 
650 4 |a electrolytes 
650 4 |a interfacial chemistry 
650 4 |a low‐temperature performance 
650 4 |a sodium‐ion batteries 
650 4 |a solvation structure 
700 1 |a Yang, Yongjian  |e verfasserin  |4 aut 
700 1 |a Yang, Yang  |e verfasserin  |4 aut 
700 1 |a Yao, Yu  |e verfasserin  |4 aut 
700 1 |a Yang, Hai  |e verfasserin  |4 aut 
700 1 |a Wu, Zhijun  |e verfasserin  |4 aut 
700 1 |a He, Shengnan  |e verfasserin  |4 aut 
700 1 |a Pan, Hongge  |e verfasserin  |4 aut 
700 1 |a Fang, Shaoming  |e verfasserin  |4 aut 
700 1 |a Rui, Xianhong  |e verfasserin  |4 aut 
700 1 |a Yu, Yan  |e verfasserin  |4 aut 
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