Sustainable Self-Healing of Perovskite Solar Cells Using Dendrimers as Volatile Reservoirs

© 2025 Wiley‐VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - (2025) vom: 13. Sept., Seite e12410
1. Verfasser: Koo, Bonkee (VerfasserIn)
Weitere Verfasser: Kim, Wooyeon, Choi, Kiwon, Huh, June, Ko, Min Jae
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2025
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article moisture stability multifunctional dendrimer perovskite degradation mechanism perovskite solar cell self‐healing perovskite
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520 |a Perovskite solar cells (PSCs) face critical challenges owing to their intrinsic instability under harsh environmental conditions. Although various strategies are explored to enhance stability, their effects remain temporary. Herein, dendrimers are designed that serve as volatile reservoirs, enabling repeated self-healing while simultaneously enhancing power conversion efficiency (PCE). PSCs containing these dendrimers achieve a PCE exceeding 26% and recover 90% of their initial PCE after ten cycles of alternating high-humidity and dry conditions. Then the self-healing mechanism is elucidated, which is facilitated by the dendrimers capturing volatile FA and interacting with PbI6 octahedra to form intermediate phases. These phenomena afford a reversible transition between perovskite and degraded perovskite phases. This approach offers a sustainable pathway toward semi-permanent PSCs by enabling continuous self-healing of perovskite materials 
650 4 |a Journal Article 
650 4 |a moisture stability 
650 4 |a multifunctional dendrimer 
650 4 |a perovskite degradation mechanism 
650 4 |a perovskite solar cell 
650 4 |a self‐healing perovskite 
700 1 |a Kim, Wooyeon  |e verfasserin  |4 aut 
700 1 |a Choi, Kiwon  |e verfasserin  |4 aut 
700 1 |a Huh, June  |e verfasserin  |4 aut 
700 1 |a Ko, Min Jae  |e verfasserin  |4 aut 
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