Molecular Orbital Level Micro-Electric Field in Green Fenton-Like Chemistry for Water Treatment : From Mechanism Understanding to Scale-Up Applications

© 2025 Wiley‐VCH GmbH.

Détails bibliographiques
Publié dans:Advanced materials (Deerfield Beach, Fla.). - 1998. - (2025) vom: 02. Sept., Seite e09280
Auteur principal: Tian, Qingbai (Auteur)
Autres auteurs: Li, Qian, Zhang, Tianran, Huang, Weixuan, Zhao, Chuanliang, Hu, Bo, Xu, Xing
Format: Article en ligne
Langue:English
Publié: 2025
Accès à la collection:Advanced materials (Deerfield Beach, Fla.)
Sujets:Journal Article Review fenton‐like chemistry mechanism understanding micro‐electric field scale‐up applications water treatment
Description
Résumé:© 2025 Wiley‐VCH GmbH.
Fenton-like systems utilizing micro-electric field-engineered catalysts have emerged as a promising technology for water remediation, demonstrating distinctive advantages via their efficient electron transport networks. This innovative approach not only significantly reduces oxidant consumption but also enables thorough mineralization of contaminants. However, current research faces critical challenges in fundamental mechanistic understanding, particularly regarding reactor scale-up strategies and biological synergy mechanisms, where a cohesive theoretical framework remains to be established. This comprehensive review systematically addresses four pivotal aspects: i) Mechanistic elucidation of charge transfer dynamics and pollutant transformation pathways in micro-electric field-enhanced Fenton systems; ii) Development of structure-activity relationship models for system optimization; iii) Implementation of modular scale-up methodologies with pilot-scale validation for engineering feasibility assessment; iv) Quantitative environmental impact evaluation using full lifecycle assessment under carbon neutrality objectives. By methodically analyzing technical bottlenecks and advancement pathways, this work establishes a theoretical foundation for advancing micro-electric field regulation in environmental remediation applications. The insights presented are expected to accelerate the development of sustainable water treatment solutions, offering innovative approaches for pollution control aligned with global carbon emission reduction targets
Description:Date Revised 03.09.2025
published: Print-Electronic
Citation Status Publisher
ISSN:1521-4095
DOI:10.1002/adma.202509280