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|a 10.1002/adma.202504553
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|a eng
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| 100 |
1 |
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|a Du, Xinwei
|e verfasserin
|4 aut
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|a Long-Lifespan and High-Rate Energy Storage Enabled by Lithium-Free Batteries with External Li Supply
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|c 2025
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|a Text
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Revised 28.08.2025
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2025 Wiley‐VCH GmbH.
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|a Energy storage batteries are pivotal for enabling reliable integration of renewable energy systems, yet further advancements in their longevity and rate performance remain imperative. Lithium (Li)-free cathode materials, while offering exceptional electrochemical stability, rate capability, and cost efficiency, face a critical limitation: the absence of active Li ions when paired with conventional graphite anodes. To address this challenge, a Li-free battery design is presented that integrates a graphite|TiS2 pouch cell architecture with a standard electrolyte modified by lithium trifluoromethanesulfinate (LiSO2CF3). This additive serves as an in situ Li-ion reservoir, electrochemically releasing Li ions during operation without generating deleterious residues or compromising structural integrity. The optimized cell achieves an unprecedented cycle life exceeding 14 000 cycles at a high current rate of 10C, alongside remarkable sustainability and cost-effectiveness. This work establishes a practical pathway for deploying long-lasting, fast-charging Li-free batteries in grid-scale energy storage applications
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|a Journal Article
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|a energy storage
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4 |
|a external Li supply
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| 650 |
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4 |
|a high‐rate
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| 650 |
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4 |
|a lithium‐free battery
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| 650 |
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4 |
|a long‐lifespan
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| 700 |
1 |
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|a Chen, Shu
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Kang, Ziyang
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zheng, Zilong
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Gao, Yue
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 37(2025), 34 vom: 10. Aug., Seite e2504553
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnas
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|g volume:37
|g year:2025
|g number:34
|g day:10
|g month:08
|g pages:e2504553
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|u http://dx.doi.org/10.1002/adma.202504553
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