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250731s2025 xx |||||o 00| ||eng c |
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|a 10.1002/wer.70106
|2 doi
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|a pubmed25n1514.xml
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|a (DE-627)NLM390336408
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|a (NLM)40738751
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Li, Xu
|e verfasserin
|4 aut
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|a Selective Removal of Soluble F From F/P-Bearing CaSO4·2H2O Slurry by CaCl2
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|c 2025
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 30.07.2025
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|a Date Revised 30.07.2025
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|a published: Print
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|a Citation Status MEDLINE
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|a © 2025 Water Environment Federation.
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|a A novel method for selectively removing F from F/P-containing CaSO4·2H2O slurry using CaCl2 as the precipitant is reported. Experimental results indicate that under conditions of 25°C, a Ca/F ratio of 2.5, and acidic pH (0.9-4.0), the F removal and P retention performance is optimal, where the removal rate of soluble F increases from 67.93% to 95.15%, while the loss rate of soluble P rises from 0% to 46.67%. At pH ≥ 6.0, the P loss rate exceeds 60%. Thermodynamic equilibrium calculations were conducted to reveal the equilibrium concentration distributions of F and P components and precipitation behavior of F and P at varying pH. At pH ≥ 4.4, binary co-precipitation of CaF2 and CaHPO4 occurs, hindering F removal while retaining P. At pH = 5.6-11.8, ternary co-precipitation of CaF2, Ca3(PO4)2, and CaHPO4 further complicates selective F removal. In contrast, at pH = 0.9-4.0, the method effectively removes F while preserving P, aligning closely with the experimental results
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|a Journal Article
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|a CaSO4·2H2O
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|a selective F removal
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|a water‐soluble F/P
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|a Calcium Chloride
|2 NLM
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|a M4I0D6VV5M
|2 NLM
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|a Phosphorus
|2 NLM
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|a 27YLU75U4W
|2 NLM
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|a Water Pollutants, Chemical
|2 NLM
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1 |
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|a Lin, Shuyu
|e verfasserin
|4 aut
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1 |
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|a Zhu, Yaoyao
|e verfasserin
|4 aut
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|a Xiang, Lan
|e verfasserin
|4 aut
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|i Enthalten in
|t Water environment research : a research publication of the Water Environment Federation
|d 1998
|g 97(2025), 8 vom: 30. Juli, Seite e70106
|w (DE-627)NLM098214292
|x 1554-7531
|7 nnas
|
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1 |
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|g volume:97
|g year:2025
|g number:8
|g day:30
|g month:07
|g pages:e70106
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|u http://dx.doi.org/10.1002/wer.70106
|3 Volltext
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