Selective Removal of Soluble F From F/P-Bearing CaSO4·2H2O Slurry by CaCl2

© 2025 Water Environment Federation.

Bibliographische Detailangaben
Veröffentlicht in:Water environment research : a research publication of the Water Environment Federation. - 1998. - 97(2025), 8 vom: 30. Juli, Seite e70106
1. Verfasser: Li, Xu (VerfasserIn)
Weitere Verfasser: Lin, Shuyu, Zhu, Yaoyao, Xiang, Lan
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2025
Zugriff auf das übergeordnete Werk:Water environment research : a research publication of the Water Environment Federation
Schlagworte:Journal Article CaSO4·2H2O selective F removal water‐soluble F/P Calcium Chloride M4I0D6VV5M Phosphorus 27YLU75U4W Water Pollutants, Chemical
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520 |a A novel method for selectively removing F from F/P-containing CaSO4·2H2O slurry using CaCl2 as the precipitant is reported. Experimental results indicate that under conditions of 25°C, a Ca/F ratio of 2.5, and acidic pH (0.9-4.0), the F removal and P retention performance is optimal, where the removal rate of soluble F increases from 67.93% to 95.15%, while the loss rate of soluble P rises from 0% to 46.67%. At pH ≥ 6.0, the P loss rate exceeds 60%. Thermodynamic equilibrium calculations were conducted to reveal the equilibrium concentration distributions of F and P components and precipitation behavior of F and P at varying pH. At pH ≥ 4.4, binary co-precipitation of CaF2 and CaHPO4 occurs, hindering F removal while retaining P. At pH = 5.6-11.8, ternary co-precipitation of CaF2, Ca3(PO4)2, and CaHPO4 further complicates selective F removal. In contrast, at pH = 0.9-4.0, the method effectively removes F while preserving P, aligning closely with the experimental results 
650 4 |a Journal Article 
650 4 |a CaSO4·2H2O 
650 4 |a selective F removal 
650 4 |a water‐soluble F/P 
650 7 |a Calcium Chloride  |2 NLM 
650 7 |a M4I0D6VV5M  |2 NLM 
650 7 |a Phosphorus  |2 NLM 
650 7 |a 27YLU75U4W  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
700 1 |a Lin, Shuyu  |e verfasserin  |4 aut 
700 1 |a Zhu, Yaoyao  |e verfasserin  |4 aut 
700 1 |a Xiang, Lan  |e verfasserin  |4 aut 
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773 1 8 |g volume:97  |g year:2025  |g number:8  |g day:30  |g month:07  |g pages:e70106 
856 4 0 |u http://dx.doi.org/10.1002/wer.70106  |3 Volltext 
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