|
|
|
|
| LEADER |
01000caa a22002652c 4500 |
| 001 |
NLM390150770 |
| 003 |
DE-627 |
| 005 |
20251017232917.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
250729s2025 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202508982
|2 doi
|
| 028 |
5 |
2 |
|a pubmed25n1602.xml
|
| 035 |
|
|
|a (DE-627)NLM390150770
|
| 035 |
|
|
|a (NLM)40714763
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a He, Hangjuan
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a High-Entropy Effect of Mesoporous Metal Oxides Promotes Tandem Catalysis for Efficient Ammonia Electrosynthesis from Nitrate
|
| 264 |
|
1 |
|c 2025
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 17.10.2025
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2025 Wiley‐VCH GmbH.
|
| 520 |
|
|
|a Electrocatalytic nitrate reduction reaction (NO3 -RR) in water offers a sustainable alternative for robust electrosynthesis of value-added ammonia (NH3) in ambient conditions. However, NO3 -RR electrocatalysis generally involves two-step tandem routes and suffers from sluggish hydrodeoxygenation kinetics, which result in a low ammonia selectivity and yield rate. In this work, it is demonstrated that the high-entropy effect of mesoporous metal oxides remarkably decreases the energy barrier of the hydrodeoxygenation route and facilitates two-step tandem electrocatalysis of NO3 -RR, which thus promotes selective NH3 electrosynthesis in an alkaline condition. By comparing a series of high-entropy mesoporous metal oxides and corresponding metal alloys and monometallic counterparts, high-entropy mesoporous (CoMnFeNiCu)3O4 discloses the highest electrocatalytic performance for efficient NH3 electrosynthesis from NO3 -RR, including remarkable NH3 Faradaic efficiency of 96.3%, high NH3 yield rate of 1.83 mmol h-1 mg-1, and excellent recycling stability of 20 cycles, representing one of the best electrocatalysts reported in the past three years. Moreover, cathode NO3 -RR performance for selective NH3 electrosynthesis is enhanced when further coupled with the thermodynamically favorable benzyl alcohol oxidation reaction at the anode. It is expected that the high-entropy effect opens up a new route to design a library of novel tandem mesoporous metal electrocatalysts for the selective electrosynthesis of various valuable chemicals from wastewater
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a NH3 electrosynthesis
|
| 650 |
|
4 |
|a high‐entropy material
|
| 650 |
|
4 |
|a mesoporous oxide
|
| 650 |
|
4 |
|a nitrate reduction
|
| 650 |
|
4 |
|a tandem catalysis
|
| 700 |
1 |
|
|a Yao, Huiqin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Sun, Lizhi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yang, Yuyang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Qiao, Zhen-An
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Liu, Ben
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 37(2025), 41 vom: 17. Okt., Seite e08982
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnas
|
| 773 |
1 |
8 |
|g volume:37
|g year:2025
|g number:41
|g day:17
|g month:10
|g pages:e08982
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202508982
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 37
|j 2025
|e 41
|b 17
|c 10
|h e08982
|