|
|
|
|
| LEADER |
01000caa a22002652c 4500 |
| 001 |
NLM389928712 |
| 003 |
DE-627 |
| 005 |
20251017232914.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
250723s2025 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202502846
|2 doi
|
| 028 |
5 |
2 |
|a pubmed25n1602.xml
|
| 035 |
|
|
|a (DE-627)NLM389928712
|
| 035 |
|
|
|a (NLM)40696959
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Zhang, Haolin
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Activating Ferroelectric-Magnetic Synergistic Effects at Cathode-Electrolyte Interfaces Toward Superfast and Stable Sodium Storage
|
| 264 |
|
1 |
|c 2025
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 17.10.2025
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2025 Wiley‐VCH GmbH.
|
| 520 |
|
|
|a Layered oxides are promising cathode candidates for sodium-ion batteries due to their high energy density. However, the rate and cycling performances are hindered by severe interfacial side reactions and sluggish kinetics. Using NaNi0.5Mn0.5O2 (NM) as a model material, ferroelectric-magnetic synergistic effects are activated at the NM-electrolyte interfaces via constructing a multiferroic layer on the NM surface, significantly realizing the superfast and stable sodium storage. First, the nucleation and growth of interfacial layers are regulated by ferroelectric-magnetic synergistic effects, resulting in the formation of a thin interfacial layer enriched with NaF. Second, a uniform sodium-ion distribution at the NM-electrolyte interfaces is established, boosting the charge transfer kinetics. Third, the distortion of NiO6 local structure is reduced, minimizing the structural change and improving the cycling stability. As a result, superior cycling (82.1% retention after 1000 cycles) and rate capabilities (up to 50-100C) in half cells, as well as high energy densities (340.7 Wh kg-1) and fast-charging properties (≈113 s per charge with ≈240.0 Wh kg-1 input) in full cells, are achieved. This work presents a novel strategy for improving rate and cycling capabilities by harnessing ferroelectric-magnetic synergistic effects, offering a pathway for designing advanced electrodes in secondary batteries
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a cycling capability
|
| 650 |
|
4 |
|a fast‐charging feature
|
| 650 |
|
4 |
|a ferroelectric‐magnetic synergistic effect
|
| 650 |
|
4 |
|a interfacial charge transfer
|
| 650 |
|
4 |
|a layered oxide cathode
|
| 700 |
1 |
|
|a Zhang, Yibing
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yan, Dong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Lv, Peng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yu, Caiyan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zheng, Haiwu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yan, Liqin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Cheng, Zhenxiang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yang, Hui Ying
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Bai, Ying
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 37(2025), 41 vom: 12. Okt., Seite e02846
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnas
|
| 773 |
1 |
8 |
|g volume:37
|g year:2025
|g number:41
|g day:12
|g month:10
|g pages:e02846
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202502846
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 37
|j 2025
|e 41
|b 12
|c 10
|h e02846
|