Nickel-Catalyzed Hydrocarboxylation of Terminal Unactivated Alkenes : Formation of Branched Carboxylic Acids and Competing Catalyst Deactivation from CO2 Reduction to CO
The reductive coupling of CO2 and alkenes represents a compelling strategy for the synthesis of carboxylic acids. In this study, we show that Ni(OAc)2 and 6,6'-Me2bpy (dmbpy) catalyzes hydrocarboxylation of terminal unactivated alkenes to afford the branched 2-methyl-substituted carboxylic acid...
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Bibliographische Detailangaben
| Veröffentlicht in: | Organometallics. - 1998. - 43(2024), 13 vom: 08. Juli, Seite 1502-1510
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| 1. Verfasser: |
Khamespanah, Fatemeh
(VerfasserIn) |
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| Weitere Verfasser: |
Gerken, James B,
Mannel, David S,
Nagy, Sandor,
Kimmich, Barbara,
Stahl, Shannon S |
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| Format: | Online-Aufsatz
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| Sprache: | English |
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| Veröffentlicht: |
2024
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| Zugriff auf das übergeordnete Werk: | Organometallics
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| Schlagworte: | Journal Article
branched carboxylic acid
carbon dioxide
carbon monoxide
hydrocarboxylation
nickel catalysis |
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