Zwitterionic Molecularly Imprinted Hairy Cellulose Nanocrystals Enable Selective Vancomycin Removal

Access to free, off-target, and nontherapeutic doses of antibiotics is a key driving factor in the emergence of antimicrobial resistance (AMR). Intravenously (IV) administered vancomycin (VAN) is among the last-line antibiotics for treating infections caused by multidrug-resistant Gram-positive bact...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 41(2025), 13 vom: 08. Apr., Seite 8554-8564
1. Verfasser: Koshani, Roya (VerfasserIn)
Weitere Verfasser: Yeh, Shang-Lin, Kheirabadi, Sina, He, Zeming, Park, Min Ju, LeConey, Sean, Read, Andrew F, Sheikhi, Amir
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2025
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Cellulose 9004-34-6 Vancomycin 6Q205EH1VU Anti-Bacterial Agents
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520 |a Access to free, off-target, and nontherapeutic doses of antibiotics is a key driving factor in the emergence of antimicrobial resistance (AMR). Intravenously (IV) administered vancomycin (VAN) is among the last-line antibiotics for treating infections caused by multidrug-resistant Gram-positive bacteria. A fraction of the total IV dose unwantedly reaches the gastrointestinal tract, driving AMR. Selective VAN removal from the complex intestinal fluid may reduce the probability of AMR emergence; however, it remains a significant challenge due to the competitive adsorption of other species. Here, we engineer novel VAN-imprinted polymerized zwitterionic hairy cellulose nanocrystals (ViPZ-HCNC) that selectively capture VAN with a removal capacity of ∼ 235 mg g-1 at an imprinting factor of ∼ 7.5. ViPZ-HCNC provide the first nanocellulose-based material with an excellent selectivity for VAN against lysine, lysozyme, and bovine serum albumin, which efficiently remove VAN from calcium ion-containing solutions and simulated intestinal fluids. Additionally, ViPZ-HCNC are not toxic against NIH/3T3 murine fibroblast cells. We envision that ViPZ-HCNC may pave the way for developing soft materials that selectively remove off-target VAN from a broad range of media, preventing VAN resistance evolution. This research is a step forward in addressing the long-lasting AMR challenge using a biobased platform 
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650 7 |a Vancomycin  |2 NLM 
650 7 |a 6Q205EH1VU  |2 NLM 
650 7 |a Anti-Bacterial Agents  |2 NLM 
700 1 |a Yeh, Shang-Lin  |e verfasserin  |4 aut 
700 1 |a Kheirabadi, Sina  |e verfasserin  |4 aut 
700 1 |a He, Zeming  |e verfasserin  |4 aut 
700 1 |a Park, Min Ju  |e verfasserin  |4 aut 
700 1 |a LeConey, Sean  |e verfasserin  |4 aut 
700 1 |a Read, Andrew F  |e verfasserin  |4 aut 
700 1 |a Sheikhi, Amir  |e verfasserin  |4 aut 
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773 1 8 |g volume:41  |g year:2025  |g number:13  |g day:08  |g month:04  |g pages:8554-8564 
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