|
|
|
|
| LEADER |
01000caa a22002652c 4500 |
| 001 |
NLM385103263 |
| 003 |
DE-627 |
| 005 |
20250509125042.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
250508s2025 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202500450
|2 doi
|
| 028 |
5 |
2 |
|a pubmed25n1377.xml
|
| 035 |
|
|
|a (DE-627)NLM385103263
|
| 035 |
|
|
|a (NLM)40033990
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a You, Zuhao
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Transparent and Conductive Polyimide-Ionene Hybrid Interlayers for High Performance and Cost-Effective Semitransparent Organic Solar Cells
|
| 264 |
|
1 |
|c 2025
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 17.04.2025
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2025 Wiley‐VCH GmbH.
|
| 520 |
|
|
|a The contradiction between high transmittance and favorable conductivity poses a great challenge in developing effective cathode interlayer (CIL) materials with sufficient thickness tolerance, which hinders the further advancement of organic solar cells (OSCs). Herein, a completely new class of alcohol processable polyimide-ionene hybrids (PIIHs) is proposed by melding pyromellitic diimide (PMD) subunits into imidazolium-based ionenes backbone covalently. These PIIHs, named PMD-DI and PMD-PD, boast high transparency, suitable energy levels, and decent conductivity. A higher PMD content endows PMD-PD with improved work function tunability, electrical properties, and crystallinity, enabling PMD-PD as CIL material with excellent thickness-insensitive characteristics, while simultaneously improving device stability significantly. Furthermore, PMD-PD also exhibits good compatibility with various electrodes and active layers, offering solar cell efficiencies of up to 19.91% and 19.29% with Ag and Cu cathodes, respectively. More importantly, the application of PMD-PD can improve the performance of semi-transparent OSCs without losing transmittance, thereby drastically enhancing the light utilization efficiency to 4.04% with an ultrathin, low-cost Cu cathode, that competes with leading optical modulation-free semitransparent OSCs with expensive Ag cathodes. This work opens a pathway to realize transparent and conductive interlayers by strategic molecular design, leading to highly efficient, stable, and cost-effective OSCs suitable for diverse applications
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a conductivity
|
| 650 |
|
4 |
|a interlayers
|
| 650 |
|
4 |
|a organic solar cells
|
| 650 |
|
4 |
|a polyimide‐ionene hybrids
|
| 650 |
|
4 |
|a transparency
|
| 700 |
1 |
|
|a Wen, Junjie
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Liu, Wenxu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Fink, Zachary
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wu, Xuefei
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Seong, Hong-Gyu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Yuxing
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Lei
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Xu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Russell, Thomas P
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Liu, Yao
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 37(2025), 15 vom: 04. Apr., Seite e2500450
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnas
|
| 773 |
1 |
8 |
|g volume:37
|g year:2025
|g number:15
|g day:04
|g month:04
|g pages:e2500450
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202500450
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 37
|j 2025
|e 15
|b 04
|c 04
|h e2500450
|